作者water0bearer (霖)
看板TransBioChem
標題Re: [化學] 99台聯大A1 19 20
時間Sat Aug 7 00:57:18 2010
※ 引述《asd789456123 (123)》之銘言:
: 19.How many mmoles of HCL must be added to 100ml of a 0.10M solution of
: methylamine(pKb=3.36)to give a buffer having a PH of 10?
: (A)8.1 (B)18.7 (C)20.0 (D)41.5 (E)12.7
: Ans:(A)8.1
pOH = pKb + log[HA]/[A-]
4 = 3.36 + log[HA]/[A-]
log[HA]/[A-] = 0.64
[HA]/[A-] = 4.2(懶的按計算機,自己估計的)
CH3NH2 + HCl ---> CH3NH3+ + Cl-
0.1*100 = 10mmole 原來CH3NH2的量
設加入Xmmole
X / (10-X) = 4.2
X差不多=8.1
: 20.Of energy, work, enthalpy, and heat, how many are stable functions?
^^^^^^ ^^^^^^^^這兩個 ^state吧!?
: (A)0 (B)1 (C)2 (D)3 (E)4
: Ans:(C)2
: 請問是哪兩個呢? 感激不盡
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◆ From: 220.136.185.78
1F:推 BIEGABOY:state function是energy和enthalpy喔!! 08/07 08:45
2F:→ BIEGABOY:work heat是path function 08/07 08:47
3F:→ mensen:大一所學的狀態函數只有兩個 其實記一下無妨 08/07 16:45
4F:→ mensen:狀態函數是和路徑無關的函數 所以q和w就不是狀態函數 08/07 16:47
※ 編輯: water0bearer 來自: 114.45.172.29 (08/07 21:10)
5F:→ water0bearer:我犯了大錯~抱歉~寫的和心裡想的不一樣...... 08/07 21:11
6F:→ asd789456123:謝謝 08/07 23:50