作者vyvyvy (yaya)
站內TransBioChem
標題[化學] 問題 台大95普化C
時間Thu Jul 5 17:37:11 2007
1.Oon mole of a liquid is vaporized at its boiling point , 65 Cand 1.00atm.
deltaHvap for the liquid is 43.8 kj/mol at 65 C
(a)Calculate w.(in unit of J)
(b)Calculate deltaE(in unit of kj)
2.thw oxidation of Cr3+ to CrO42- can be accomplished using Ce4+ in a
buffered solution.the following data were obtained:
Initial rate [Ce4+] [Ce3+] [Cr3+]
1 2x10-3 1x10-2 3x10-2
2 4x10-3 2x10-2 3x10-2
3 4x10-3 1x10-2 3x10-2
4 8x10-3 2x10-2 6x10-2
(a)Calculate the order in the rate law of the species Ce4+
(b) Ce3+
(c) Cr3+
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