作者lrfnc (霂)
看板Chemistry
標題Re: [學科] 普通化學問題~ 氣體方面..
時間Sat Nov 10 01:00:28 2007
※ 引述《walk0123 (誓言)》之銘言:
: 在0.959atm和298K狀態下,一個由C和H所組成的樣本
: 在燃燒之後,可以得到一1.51atm和375K的CO2和H2O的混合氣體,
: 此混合氣體的密度是1.39g/L
: 且混合物的氣體體積是原來純碳氫化合物的4倍,
: 問碳氫化合的分子式?
: 答案是C2H6。
: 要如何計算~????
: 原始題目如下!
: Consider a sample of a hydrocarbon(a compound consisting of only carbon and hydrogen) at 0.959 atm and 298 K.
: Upon combusting the entire sample in oxygen,
: you collect a mixture of gaseous carbon dioxide and water vapor at 1.51 atm and 375K.
: This mixture has a density of 1.391 g/L and occupies a volume four times as large as that of the pure hydrocarbon.
: Determine the molecular formula of the hydrocarbon.
P V = n R T
n = (P V)/(R T)
n前 : n後 = (0.959*V)/(0.082*298) : (1.51*4V)/(0.082*375)
= 1 : 5
設sample分子式為CaHb,且初始有 1 mol
CaHb + (a+b/4) O2 ---> a CO2 + b/2 H2O
得 a + b/2 = 5 -----(1)
由氣體密度得===>
(44a + 9b)/4V = 1.39
V = (0.082*298*1)/0.959
= 25.48
將V帶回得===>
44a + 9b = 142 -----(2)
由(1),(2)式可得, a = 2
b = 6
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我是這樣算的@@
不知道對不對
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1F:推 walk0123:嗯嗯~~~好像對耶~~~太感謝你了~~~~^^ 11/10 01:25