作者vitamin1003 (小翔)
看板Chemistry
標題Re: 請問判斷無機光學活性
時間Sun Jan 14 21:40:58 2007
※ 引述《happysister (...)》之銘言:
: 瘋狂讀讀看的無機
: 裡面在群論那一節有一題92中興
: Which of the following symmetry elements is the best criteria for chirality?
: A inversion center
: B mirror plane
: C proper rotation axis
: D improper rotation axis
: 它寫答案是b
: 可是對稱元素裡若有sigma或其他的非徵轉軸(i,Sn..)不就沒有光學了嗎??
: 一開始光學的定義不就是...In general,we can say that a molecule or some other
: object is chiral if it has no symmetry operations(other than E)or if it has
: only proper rotation axes.
: 麻煩大家了...>"<
見 Huheey
Optical active molecules must be dissymmetry
Dissymmetry : molecule with no improper rotation axis
所以只要判斷有無 improper rotation axis 就可知道是否為光學活性
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