作者n0204159 (黄黑人)
看板TransBioChem
标题[化学] 96台大转考普化A 第6题
时间Sat Dec 13 11:33:14 2008
For hydrogen-like atoms the wavefunctions for the 1s and 3s orbitals are
Ψ(1s)=π^-1/2(Z/ao)^3/2 e^-σ
Ψ(3s)=(3^-9/2) π^-1/2(Z/ao)^3/2(27-18σ+2σ^2)e^-σ/3
in which σ=Zr/ao,ao=5.29x10^-11m
(a) determine the radius of the most probable radial probability of the 1s
state
(b) calculate the position of the nodes for the 3s states
(c) calculate the relative probability ratio of finding the eletron between
1s and 3s states centered at the nucleus (ie. the origin position)
(d) for the 1s and 3s states,calculate their relative probability ratio of
finding the electron in a shell located at a radius distance of 300pm
请各位高手为不才解惑
谢谢!!
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1F：推 glass564:我这里有我自己写的解答 这题要用薛丁格 12/14 10:23
2F：→ glass564:光这题我当时就想了一个多小时 12/14 10:24
3F：→ n0204159:那可以请你把解答打上来吗? 一个多小时...那你时间够吗? 12/14 10:40
4F：推 yang770610:r=a0/z σ=7.1 or 1.9 01/07 21:05