作者hank0526 (美国队长)
看板NTU-Exam
标题[试题] 101上 陈昭岑 有机化学第一次小考
时间Tue Jan 15 22:09:46 2013
课程名称︰有机化学
课程性质︰必修
课程教师︰陈昭岑
开课学院:工学院
开课系所︰化工系
考试日期(年月日)︰2012/12/25
考试时限(分钟):20mins
是否需发放奖励金:是
(如未明确表示,则不予发放)
试题 :
1. Compound A has the formula C8H12and is optically active. It reacts with
hydrogen in the presence of platinum metal to give B, which has the formula
C8H18 and is optically inactive. Careful hydrogenation of A using Lindlar
catalyst (Pd/BaSO4/quinoline/S) gives C, which has the formula C8H14and is
optically active. Compound A reacts with sodium in ammonia to give D which
also has the formula C8H14 and is optically active. What is compound A?
图
http://ppt.cc/Kp9I
2. The reaction of isobutylene (CH3)2C=CH2 with methanol in the presence of
mercuric diacetate will give (A) tert-butyl methyl ether; (B) isobutyl methyl
ether; (C) tert-butyl acetate; (D) isobutyl acetate
3.Devise a sensible synthetic pathway to prepare 3-phenyl-3-pentanol
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