课程名称︰有机金属化学 课程性质︰选修 课程教师︰刘绪宗 开课学院：理学院 开课系所︰化学系 考试日期（年月日）︰98/06/17 考试时限（分钟）：120 是否需发放奖励金：yes （如未明确表示，则不予发放） 试题 : 命题者︰客座副教授 西原康师 Answer the following questions.(注) Chapter 1 Describe each advantages and disadvantages points in the homogeneousand the heterogeneous catalysts. (You may draw the table, or write sentences.) Chapter 2 Explain with the figures in detail by selecting two from the following fundamental five reactions in organometallic chistry. (oxidative addition, reductive elimination, migratory insertion, β-hydrogen abstraction, and transmetallation.) Chapter 3 There exist four types of hydroformylation reactions (oxo process) with the homogeneous catalysts. Explain one of them in detail. Chapter 4 Show three equations and the net equation in the Monsanto processes. Chapter 5 Describe reaction schemes and their catalytic cycle in the Ni-catalyzed addtion reaction of HCN to buta-1,3-diene as much as you can. (You may draw the scheme, or write sentences.) Chapter 6 Explain the Ziegler-Natta catalyst by using all of the following vocabularies. (co-catalyst, polypropylene, and active site.) Chapter 7 Select one of the following three persons, and explain in detail the contents of his chemistry related to the Noble Prize in Chemistry in 2001. (Knowles, Noyori, Sharpless) Chapter 8 Write the impression to the class in English by Japanese professor. 注︰试题中的章节是Robin Whyman, Applied Organometallic Chemistry and Catalysis, Oxford University Press书中的内容 (不过考试是close book) --

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