作者HLiNaKRbCsFr (醒醒吧 阿宅)
看板Electronics
标题Re: [问题] 请教两个问题---太阳能电池的
时间Sun Jan 7 16:24:43 2007
1.想请教为什麽长波长的光能穿透的较深入??
2.将金属电极埋入基板中,以减少串联电阻。
最近读的资料好像能回答 整理出来给有兴趣的同志们参考看看
(第一题的) 以下为资料节录 (同时感谢duffrose板友、rainstonein板友 推文提供意见)
http://img204.imageshack.us/img204/9633/solarcelloperationprincfc5.jpg
At long wavelengths, around 1-1.2μm, the absorption coefficient α of Si
is small and the absorption depth (1/α) is typically greater than 100μm.
To capture these long-wavelength photons, we therefore need a thick p-side
and at the same time a long minority carrier diffusion length Le.
(第二题的)
the photogenerated electrons have to traverse a surface semiconductor region
to reach the nearest finger electrode. All these electron paths in the
n-layer surface region to finger electrodes introduce an effective series
resistance Rs into the photovoltaic circuit.
http://img225.imageshack.us/img225/2400/rsrpbm0.jpg
实际应用时, 为了使入射面积达到最大, 通常会把手指电极做的更细
但这样却会使串联电阻增加 (感谢algebra板友推文提供的意见)
上述在资料中也有提到:
If the electrodes are thin, then the resistance of the electrodes themselves
will further increase Rs. (R 反比於A)
基於此, 所以将电极嵌埋於n-side, 以增加电子流接触电极的面积
http://img204.imageshack.us/img204/3804/mosaicedni0.gif
因为转换效率η= FF*Isc*Voc/Pin
图中可看出, 虽然串联电阻值的上昇对开路电压及短路电流几乎没有影响,
http://img73.imageshack.us/img73/9320/characteristicdeviationck9.jpg
却使得fill factor 大幅下降, 进而降低电池转换隙率.
以上, 有错请指教. ( ̄□ ̄")a
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