作者cliffe31013 (fish-ball)
看板Chemistry
标题[学科] 物理化学程序的三个问题
时间Wed Apr 23 11:13:29 2008
1. A CSTR is designed for a first-order reaction.
(1)Develop the equation to describe the relationship among the concentration
in the in flow(Co), the concentration in the effluent(C) and hydraulic
detention time (X), whlie X=V/Q
(2) If the required removal or conversion is 90% and reaction rate constant,
k, is 0.5/hr, what's the detention time for this CSTR?
(3)Repeat the problem (2), except that k is 0.75/hr
2. For the reversible reaction,
2A<-->B
batch type experiments with different inital concentration (Co) were conducted.
The results are as followed:
C(mmol/L)
t(min) Co=50mmol/L Co=100mmol/L
1 45 91
3 37 76
5 33 68
10 31 63
Determine the rate law for the forward reaction at the initial time.
3.The concentration of compound A in a beaker with well mixing is varied with
time as the following table.
t(min) C(mmol/L)
0 100
5 85
10 78
20 72
50 65
(1)Determine K1 and a (reaction order)
(2)If Co = 500 mmol/L, C = 10 mmol/L , Q = 2m3/hr , calculate the reactor volume
required for (A)CSTR (B)PFR.
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