作者fantasywater (狂想)
看板Chemistry
标题可否帮忙解释一下史雷特规则
时间Sat Nov 4 22:09:57 2006
Slater's Rules for Calculating Shielding1
1.for [ns, np] e-s, e-s to the right in the modified electronic configuration
contribute nothing
2. for [ns, np] e-s, other electrons of same group contribute 0.35 each
(except 1s, 0.3)
3. each electron in n - 1 group, contribute 0.85
4. each electron in n - 2 group, contribute 1.0
5. nd & nf group, rules 1 & 2 remain the same, all electrons to the left
contribute 1.0modified electronic configuration
[1s][2s2p][3s3p][3d][4s] etc
英文实在是不好,可以帮忙解释一下吗 orz
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