作者GOPOL (爬不起来阿!!)
看板Chemistry
标题请问一题关於热力学的问题
时间Tue Feb 7 23:45:33 2006
in the plot of enthalpy VS temperature for metals A and B
if the slope of A less than B which of the following is true
(A)the entropy of A is less than B
(B)melting point of metal A is higher than that of metal B
(C)more heat is needed to heat up metal B than A when the equal
moles of A and B are used
(D)heat will flow from B to A when they are in direct contact
请化学高手指教一下 这一题不太懂
谢谢
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1F:推 ast154251:此斜率等於热容 02/07 23:52
2F:推 CHHO:C 02/08 10:36
3F:推 lofishive:Capacity= H 对 T之偏微分 (固定P or V) 02/08 13:45
4F:推 Obiwang:V不用固定吧... 02/08 14:52
5F:推 ast154251:P或V一定要固定其一,否则热容无法定义 02/08 22:15
6F:→ lofishive:应该说:根据Legendre转换下 使用固定P的状况较常用 02/08 23:29
7F:推 Obiwang: 唔.我只会从 dH = VdP + TdS 来想耶。定V是怎样的情况阿? 02/09 00:31
8F:推 reckson1017:楼上的我有写解释参考看看 02/09 00:53